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Hydrometallurgy > 2011 > 108 > 3-4 > 177-188
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Wensheng Zhang
Chu yong cheng.
Titanium Titanium dioxide Titanium pigment
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A review on metallurgical issues in the production and welding processes of clad steels.
1. Introduction
2. metallurgy of as-produced clad steel plates, 2.1. hot rolled clad steel plates.
- Preheating of the assembled pack, with a slow increase from room temperature up to 1230 °C, maintained for 5 h;
- Hot rolling between 1230 and 850 °C, followed by air cooling;
- Disassembling of the rolled pack;
- Final annealing in the range 920–950 °C, followed by air cooling.
2.2. Explosion-Welded Clad Steel Plates
2.3. weld overlaid clad steel plates, 3. fusion welding of clad steel, 3.1. arc welding processes (hybrid multi-passes), 3.2. laser and hybrid laser/arc processes, 4. discussion, 5. conclusions and future directions.
- Dilution between the filler and base metal at the level of the base and clad steel, as well as dilution between the deposited layers in multi-pass welding;
- Unexpected composition of the welds;
- Solidification in non-optimal mode to ensure crack-free welds;
- Carbide enrichment in the ferritic phase, followed by martensitic transformation during cooling;
- Carbide precipitation in the austenitic phase, followed by local hardening and sensitization to intergranular corrosion as a function of the time permanence within the critical interval of temperature.
Author Contributions
Data availability statement, conflicts of interest.
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Click here to enlarge figure
Welding Process | Welding Procedure | Welding Sequence | Filler Geometry | Weld Cross-Section Shape | Dilution Rate |
---|---|---|---|---|---|
Arc welding | Multi-pass | Starting from base metal | Wire | Wide | High |
LBW | Single pass | - | Wire/strip | Narrow | Low |
Hybrid (laser/arc) | Single pass | - | Wire/strip | Very wide at arc side | Low at laser side/high at arc side |
Weld Overlay Process | Dilution (%) [ ] | Fe (%)/Cladding Layer Thickness (mm) [ ] |
---|---|---|
SAW | 30–70 | - |
GMAW | 13–33 | 13–26.9/3–3.5 |
SMAW | 13–20 | 22–23.4/3–4 |
GTAW | 13–20 | 12.6/- |
GTAW-HW | 10–40 | 6.6–23.7/1.6–3.5 |
CMT | - | 1–4.1/3 |
Solidification Modes | Transformations | Composition Limits (Cr /Ni ) | Microstructures |
---|---|---|---|
Austenitic (A mode) | L → L + γ → γ | <1.25 | Fully austenitic |
Austenitic/ferritic (AF mode) | L → L + γ → L + δ + γ → γ + δ | 1.25–1.48 | Austenitic with ferrite at cell and dendrite boundaries |
Ferritic/austenitic (FA mode) | L → L + δ → L + δ + γ → δ + γ | 1.48–1.95 | Skeletal and/or lathy ferrite from F-A solid-state transformation |
Ferritic (F mode) | L → L + δ → δ + γ | >1.95 | Ferrite matrix and Widmastänstatten austenite |
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Giudice, F.; Missori, S.; Scolaro, C.; Sili, A. A Review on Metallurgical Issues in the Production and Welding Processes of Clad Steels. Materials 2024 , 17 , 4420. https://doi.org/10.3390/ma17174420
Giudice F, Missori S, Scolaro C, Sili A. A Review on Metallurgical Issues in the Production and Welding Processes of Clad Steels. Materials . 2024; 17(17):4420. https://doi.org/10.3390/ma17174420
Giudice, Fabio, Severino Missori, Cristina Scolaro, and Andrea Sili. 2024. "A Review on Metallurgical Issues in the Production and Welding Processes of Clad Steels" Materials 17, no. 17: 4420. https://doi.org/10.3390/ma17174420
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- DOI: 10.1016/J.HYDROMET.2011.04.005
- Corpus ID: 98410464
A literature review of titanium metallurgical processes
- Wensheng Zhang , Zhaowu Zhu , C. Cheng
- Published 1 July 2011
- Materials Science, Engineering
- Hydrometallurgy
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Wensheng Zhang Zhaowu Zhu C. Cheng
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A review of wire and arc additive manufacturing using different property characterization, challenges and future trends
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- Published: 29 August 2024
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- Jyothi Padmaja Koduru ORCID: orcid.org/0009-0009-8455-6922 1 ,
- T. Vijay Kumar 2 &
- Kedar Mallik Mantrala 3
Because of the reasonability of economically generating large-scale metal equipment with a very large rate of deposition, important development has been conducted in the learning of the “wire arc additive manufacturing (WAAM)” approach also the mechanical and microstructure features of the fabricated elements. The WAAM has emerged highly so the large range of the materials has accompanied the operation and its development fighting. It has enhanced as a very significant mechanism for the large metal equipment in various manufacturing organizations. Because of its arc-assisted deposition, high process cycle time, process stability, defect monitoring, and management are severe for the WAAM device to be employed in the organization. High improvements have been performed in the development of the process, control system, comprehensive operation monitoring, material evaluation, path slicing, and programming but still, it demands the improvement. Therefore, this article aims to give a detailed review of the WAAM systems to facilitate an easy and quick understanding of the current status and future prospects of WAAM. The stage-wise implementation of WAAM, usage of metals and alloys, process parameter effects, and methodologies used for improving the quality of WAAM components are discussed. The usage of hardware systems and technological parameters used for understanding the physical mechanism are also described in this research work. In addition, the monitoring systems such as acoustic sensing, optical inspection, thermal sensing, electrical sensing, and multi-sensor sensing are analyzed and the property characterization techniques also be evaluated in this study. On the other hand, the additive as well as the subtractive technologies and the artificial intelligence techniques utilized for improving the manufacturing level are discussed. Finally, the possible future research directions are provided for making further developments in WAAM by the researchers.
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Jyothi Padmaja Koduru
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Koduru, J.P., Kumar, T.V. & Mantrala, K.M. A review of wire and arc additive manufacturing using different property characterization, challenges and future trends. Int J Syst Assur Eng Manag (2024). https://doi.org/10.1007/s13198-024-02472-y
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DOI : https://doi.org/10.1007/s13198-024-02472-y
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The processes for production of pigment grade TiO 2 and titanium metal are schematically presented in Fig. 1. There are two processes to manufacture titanium pigment: the sulphate process and the chloride process. The two processes differ in both their chemistry and raw material requirements (Hamor 1986).
Research highlights. Various titanium metallurgical processes for the production of titanium dioxide and titanium metal have been reviewed and compared including: Processes to upgrade ilmenite to synthetic rutile. Thermo-chemical Kroll and Hunter processes. Electro-chemical processes for direct reduction of TiO 2 and electro-slag and in-situ ...
Various titanium metallurgical processes have been reviewed and compared for titanium dioxide and titanium metal, mainly focusing on the future development of hydrometallurgical processes. It is ...
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For several decades, the metallurgical industry and the research community worldwide have been challenged to develop energy-efficient and low-cost titanium production processes. The expensive and energy-consuming Kroll process produces titanium metal commercially, which is highly matured and optimized. Titanium's strong affinity for oxygen implies that conventional Ti metal production ...
In this work, a consumable anode composed of a solid solution of titanium carbide and titanium monoxide was prepared via carbothermic reduction of TiO2. Upon electrolysis, the anode fed Ti2+ into solution and carbon monoxide was generated; no excess carbon remained to contaminate the melt. On the cathode, high-purity titanium (>99.9%) was produced. Our results suggest anode and cathode current ...
Today, Discontinuously Reinforced Particulate Titanium Matrix Composites (DRPTMCs) have been the most popular and challenging in consideration with development and heat treatment due to their significant weight-saving capacity, high specific strength, stiffness and oxidising nature compared with other metals and alloys. Owing to their excellent capabilities, DRPTMCs are widely used in ...
Fig. 1. A schematic of processes for the pro - "A literature review of titanium metallurgical processes" Skip to search form Skip to main content Skip to account menu ... {A literature review of titanium metallurgical processes}, author={Wensheng Zhang and Zhaowu Zhu and Chu Yong Cheng}, journal={Hydrometallurgy}, year={2011}, volume={108 ...
Abstract: For several decades, the metallurgical industry and the research community worldwide. have been challenged to develop energy-efficient and low-cost titanium production processes. The ...
Due to the strong chemical affinity of titanium to oxygen, effective deoxygenation of Ti has always been a challenge. This paper aims to provide a cursory review of different methods for deoxygenation that have been reported in literature to date. For more comprehensive treatment of the subject the readers are referred to [12, 15, 19, 20]. 2.
Additive manufacturing, or 3D printing, is a process where a part is produced layer by layer, and represents a promising approach for designing components close to their final shape. Titanium alloys produced by additive manufacturing find application in various industries. This overview examines the features of the formation of the microstructure and properties in Ti alloys synthesized with ...
The ilmenite contains 40 65% titanium as TiO2, with the rest. - being iron oxide. The Becher process removes the iron oxide, leaving a residue of synthetic rutile, which contains more than 90% TiO2. A schematic owsheet comprising four major steps: oxidation, reduc-fl tion, aeration and acid leach is shown in Fig. 2.
This paper reviews and compares the three major processes for producing titanium metal sponge: the Kroll process which uses magnesium for the reduction of TiCl4 to titanium metal, the Hunter process which uses sodium for the reduction, and electrowinning which is a direct reduction using electrical energy. The paper also discusses the production of TiCl4 from ore and explains the various ...
A Literature Review of Titanium Metallurgical Processes - Free download as PDF File (.pdf), Text File (.txt) or read online for free. Various titanium metallurgical processes have been reviewed and compared for titanium dioxide and titanium metal. Many processes are commercially used or proposed to upgrade ilmenite to synthetic rutile. Novel BHP Billiton sulphate processes have been developed.
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The near-complete dissociation of titanium with oxygen in Ti O solid solution via direct reduction is difficult, resulting in that the energy-intensive and costly Kroll process is the only mature method to produce Ti metal. In the Kroll process [2], oxygen initially combined with titanium in the titanium slag or synthetic rutile is removed in ...
Focusing mainly on ferritic steel plates clad with austenitic steel, this article aims to review the scientific literature of recent years which deals with both the production and the fusion welding processes. The metallurgical issues concerning the interfaces and the effects of microstructural characteristics on mechanical behaviour and ...
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Because of the reasonability of economically generating large-scale metal equipment with a very large rate of deposition, important development has been conducted in the learning of the "wire arc additive manufacturing (WAAM)" approach also the mechanical and microstructure features of the fabricated elements. The WAAM has emerged highly so the large range of the materials has accompanied ...
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