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4 subst groups radiate from the chirality center. Subst priority is determined by atomic number, working outward from the chirality center. To assign priorities, we must compare the chain atimes and thier sets of attached atoms, c(x,y,z), starting from the first point of attachment to the chirality center and moving outwards along each chain.

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Step-by-step solution. Step 1 of 2. (a) Atoms to form a bond, come closer with release of energy, but at a certain distance, it release of energy gets stopped. That certain distance for two atoms is called Bond Length. For the case below, the bond is weaker comparatively, hence the distance will be more, so the bond length will be more, hence ...